"Messi and Cristiano Ronaldo have gone above the norm, when they're scoring 50 or 60 goals a season", said Kane.
"It's a good chance to win and focus on ourselves, maybe there's some pressure, but we want to show that people are wrong", Kane said in his pre-match press conference.
Leganes came back from a goal down to beat the Spanish champions on Wednesday night, September 26, which was Barcelona's first defeat this season in La Liga.
"He's set the standard".
"As a striker I want to try and match that".
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The World Cup victor missed his side's Champions League opener, as they let slip a one-goal advantage in the closing stages to lose 2-1 to Inter in Milan.
England stars, Kieran Trippier and Danny Rose were used at wing-back in their last game over the weekend, but Pochettino likes to rotate that department, so one or both of Serge Aurier and Ben Davies could return.
"It's very clear, very simple, we need to be near him when he gets the ball", he added.
Argentina's Messi now holds multiple scoring records, including the most goals in a calendar year. We must play on Monday against City and then Wednesday or Thursday and then on Saturday again.
Spurs go into the match after three successive wins in all competitions while Barca are without a victory in their last three games.
Last season Tottenham ensured qualification for the knockout stage with a memorable 3-1 win over Real Madrid at Wembley but Pochettino thinks it will be hard to replicate the performance against Barcelona.